PRODUCTION OF SILICON CARBIDE BY SPARK PLASMA SINTERING
Annotation
This article investigates the synthesis of silicon carbide through the efficient processing of microsilica, a technogenic waste by-product of silicon production at «Tau-Ken Temir» LLP. High-purity microsilica and P804T-grade carbon were utilized as the starting components. The powder mixture was blended in a WiseMix BML-2 planetary mill at 200 rpm for 24 hours, followed by processing in a «Labox 650, Sinter Land» spark plasma sintering system. Sintering was conducted at a temperature of 1800 °C, a pressure of 50 MPa, and a holding time of 10 minutes. Thermodynamic analysis, performed using the Thermo-Calc software package, demonstrated that 1800 °C is the optimal temperature for silicon carbide formation in the Si-C-O system. Furthermore, the results confirm that the selected technological parameters intensify reaction kinetics and ensure complete phase transformations. The study revealed that the resulting material possesses high density (3.22 g/cm³), hardness (286 HB), and a homogeneous nanostructure. According to X-ray diffraction (XRD) analysis, the predominant phase is β-SiC (98.2 %). Microstructural studies showed that the average particle size is 108.4 nm, and the material is characterized by a dense, virtually defect-free structure without pores. The absence of electrical conductivity (<0.5 MS/m) indicates high material purity. These results demonstrate the effectiveness of the spark plasma sintering method for converting metallurgical waste into high-value-added materials, while also confirming the potential of this technology for energy conservation and environmental optimization of production.
Author
K. Tuyskhan
G.E. Akhmetova
G.A. Ulyeva
DOI
https://doi.org/10.48081/BGQF2238
Keywords
silicon carbide
microsilica
spark plasma sintering
carbothermic reduction
metallurgical waste
nanostructured material
Year
2026
Номер
Issue 2
195
0
For citation:
K. Tuyskhan, G.E. Akhmetova, G.A. Ulyeva PRODUCTION OF SILICON CARBIDE BY SPARK PLASMA SINTERING // Scientific journal "Science and Technology of Kazakhstan". - 2026 - №2 - Р. 381-392. https://doi.org/10.48081/BGQF2238
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