IMPACT OF MECHANOACTIVATION ON STRUCTURE OF WC-Fe and WC-Ni COMPOSITES
Annotation
This study investigates the effect of mechanical synthesis duration on the morphological and structural characteristics of tungsten carbide (WC)-based composite powders alloyed with iron (Fe) and nickel (Ni). Four compositions were synthesized: WC88–Fe12, WC95–Fe5, WC88–Ni12, and WC95–Ni5. Mechanical activation was performed in an argon atmosphere at a rotation speed of 500 rpm for 1, 2, and 4 hours. Particle size distribution analysis was conducted, and the median particle diameter (D₅₀) was determined to assess the evolution of particle size with increasing milling time. It was found that prolonged mechanical treatment led to particle coarsening, especially in systems with high WC content (95 wt.%), where after 4 hours of milling, noticeable powder agglomeration and adhesion to the container walls and grinding balls occurred.
The particle morphology was examined using scanning electron microscopy (SEM), and the results were consistent with the granulometric data. At the early stages of mechanical synthesis, efficient particle fragmentation was observed; however, with longer milling durations, particle agglomeration occurred. Fine particles began to stick together, forming loose agglomerates, leading to an increase in aggregate size due to mechanochemical interactions and interparticle adhesion.
X-ray diffraction (XRD) analysis revealed a decrease in peak intensity and broadening of the diffraction lines corresponding to WC and metallic phases, indicating a reduction in crystallinity, crystallite size refinement, and an increase in lattice defects. The obtained results made it possible to determine the optimal conditions of mechanical synthesis for producing homogeneous powder mixtures suitable for subsequent sintering.
Author
Y.A. Kizatova
A.S. Kizatov
M.T. Aidarova
Sherzod Kurbanbekov
L.B. Bayatanova
DOI
https://doi.org/10.48081/GMBM5273
Keywords
tungsten carbide
iron
nickel
mechanosynthesis
powder composites
morphology
structural characteristics
Year
2025
Номер
Issue 3
469
6
For citation:
Y.A. Kizatova, A.S. Kizatov, M.T. Aidarova, Sherzod Kurbanbekov, L.B. Bayatanova IMPACT OF MECHANOACTIVATION ON STRUCTURE OF WC-Fe and WC-Ni COMPOSITES // Scientific journal "Science and Technology of Kazakhstan". - 2025 - №3 - С. 277 – 291. https://doi.org/10.48081/GMBM5273
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