MODELING THE REDUCTION OF LATERITIC NICKEL ORE FROM THE «BATAMSHA» DEPOSIT USING GASEOUS REDUCERS IN THE «HSC CHEMISTRY 10» SOFTWARE PACKAGE
Annotation
The article presents a simulation of the low-temperature solid-phase reduction process of nickel laterite ore from the "Batamsha" deposit using the "HSC Chemistry 10" software package. X-ray phase analysis determined the phase composition of the nickel ore: 1.43% NiO, 5.2% Fe₂O₃, 9.4% Fe₃O₄, 6% FeO·OH, 5.4% Fe₂SiO₄, 0.27% FeS, 4.2% MgSiO₃, 12.4% Mg₃Si₂O₅(OH)₄, 35.1% CaAl₂Si₂O₈, 17.8% SiO₂, and 2.8% CaCO₃. The obtained data were used to calculate the molar composition of the nickel ore, necessary for determining the number of moles of components involved in the reduction reactions of oxide compounds in the ore, utilizing the "HSC Chemistry 10" software package. The thermodynamics of the reduction process was studied using the Equilibrium Composition module, which calculates the equilibrium compositions of interacting phases based on the Gibbs free energy minimization method. The reduction of nickel laterite ore was investigated using carbon monoxide and its mixtures with hydrogen in ratios of (1:1), (1:2), and (1:3). The study using carbon monoxide as a reducing agent showed that nickel reduction begins at 440 °C, with complete reduction achieved at a reductant consumption of 1.1 moles at a temperature of 900 °C. The research demonstrated that adding hydrogen to CO significantly lowers the reduction onset and complete reduction temperatures of nickel (from 440/900 °C to 340/700 °C) as well as the required reductant consumption. In all experiments, iron reduction began at 440 °C, indicating selective nickel reduction when using CO-hydrogen mixtures. The CO+H₂ reducing mixture in a 1:2 ratio can be considered optimal in terms of balancing reduction efficiency and economic process parameters. The obtained results indicate the potential of using hydrogen-containing reducing mixtures to improve the efficiency of nickel extraction from laterite ores. However, the optimal mixture composition depends on the specific characteristics of the ore and technological conditions.
Author
A.A. Abilberikova
D.A. Yessengaliyev
Ye.K. Kuatbay
B.S. Kelamanov
K. Benzesik
DOI
https://doi.org/10.48081/HVTA9346
Keywords
lateritic nickel ore
low-temperature selective reduction
hydrogen
carbon monoxide
modeling of reduction
Year
2025
Номер
Issue 1
549
10
For citation:
A.A. Abilberikova, D.A. Yessengaliyev, Ye.K. Kuatbay, B.S. Kelamanov, K. Benzesik MODELING THE REDUCTION OF LATERITIC NICKEL ORE FROM THE «BATAMSHA» DEPOSIT USING GASEOUS REDUCERS IN THE «HSC CHEMISTRY 10» SOFTWARE PACKAGE // Scientific journal "Science and Technology of Kazakhstan". - 2025 - №1 - С. 193 – 208. https://doi.org/10.48081/HVTA9346
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